Hexaaquacobalt(II) 5,5′-(propane-1,3-diyldithio)bis(1H-tetrazole-1-acetate)
نویسندگان
چکیده
The asymmetric unit of the title complex, [Co(H(2)O)(6)](C(9)H(10)N(8)O(4)S(2)), contains one-half of a [Co(H(2)O)(6)](2+) cation and one-half of a 5,5'-(propane-1,3-diyldithio)bis-(1H-tetra-zole-1-acetate) (battp(2-)) anion. The Co(II) center is coordinated by six H(2)O mol-ecules in a distorted octa-hedral coordination environment. In the crystal structure, intra- and inter-molecular O-H⋯O and O-H⋯N hydrogen bonds link the cations and anions into a three-dimensional network. π-π contacts between the tetra-zole rings [centroid-centroid distance = 3.346 (1) Å] may further stabilize the structure.
منابع مشابه
catena-Poly[[[bis[2,2′-(propane-1,3-diyldithio)bis(1,3,4-thiadiazole)-κN 4]copper(II)]-bis[μ-2,2′-(propane-1,3-diyldithio)bis(1,3,4-thiadiazole)-κ2 N 4:N 4′]] bis(perchlorate)]
In the title compound, {[Cu(C(7)H(8)N(4)S(4))(4)](ClO(4))(2)}(n), the Cu(II) atom, occupying a crystallographic inversion centre, is six-coordinated by six N atoms of three symmetry-related 2,2'-(propane-1,3-diyldithio)bis-(1,3,4-thia-diazole) (L) ligands in a slightly distorted octa-hedral geometry. The ligand L adopts two kinds of coordination modes in the crystal structure; one is a monodent...
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